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Download e-book for iPad: Anion receptor chemistry by Jonathan L Sessler

By Jonathan L Sessler

ISBN-10: 0854049746

ISBN-13: 9780854049745

Anion popularity performs a serious position in various organic methods, and quite a few receptors and providers are available in the course of the wildlife. Chemists operating within the region of supramolecular chemistry have created more than a few anion receptors, drawing idea from nature in addition to their very own cutting edge strategies. This e-book lines the origins of anion reputation chemistry as a special sub-field in supramolecular chemistry, whereas illustrating the fundamental techniques at the moment getting used to impact receptor layout. the mix of a organic evaluate and precis of present man made techniques offers a insurance that's either accomplished and understandable. First, the authors aspect the main layout motifs which were used to generate man made receptors and that are prone to give you the foundation for extra advancements. in addition they spotlight in short many of the positive factors which are found in naturally-occurring anion acceptance and delivery structures and summarise the functions of anion acceptance chemistry. offering an in depth assessment for practitioners within the box and a concise advent to the subject for novices, Anion Receptor Chemistry displays the present nation of this intriguing examine region. Fully-referenced and illustrated in color, it's a welcome boost to the literature.

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Extra resources for Anion receptor chemistry

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12a). The receptor in this structure is considerably distorted, a finding that was thought to reflect the reduced stability of the complex. 7. 6, with the addition that the chloride anion is shown in green Another early pioneer in the anion recognition arena is Schmidtchen from the Technische Universität München. 53 Instead, these receptors employ quaternary ammonium groups arranged in a tetrahedral manner. 9) solely by electrostatic interactions. By altering the length of the alkyl chain between the ammonium centres, Schmidtchen was able to “tune” the selectivity of the receptors for particular halides.

Int. , 1994, 33, 327; K. P. Schmidtchen, Angew. Chem. Int. , 1995, 34, 65. A. Pascal, J. V. , 1986, 27, 4099. S. J. Engbersen, W. N. Reinhoudt, Angew. Chem. Int. , 1993, 32, 900. J. V. S. , 1992, 35, 6085. qxd 26 2/7/2006 12:18 PM Page 26 Chapter 1 58. B. M. -M. G. L. Fyles, J. Chem. Soc. Chem. , 1978, 934. 59. G. Müller, J. P. Schmidtchen, Angew. Chem. Int. , 1988, 27, 1516. 60. J. J. Clive, D. B. L. M. King, J. C. B. Woodward, J. Am. Chem. , 1983, 105, 6429. 61. M. Shionoya, H. Furuta, V. Lynch, A.

Dijkhuizen and B. Witholt, Appl. Environ. , 1985, 49, 673; S. B. Janssen and B. Witholt, J. , 1985, 163, 635; C. Wischnak and R. Muller, Biotechnology, 2000, 11b, 241. R. Dutzler, B. Campbell Ernest, M. Cadene, T. Chait Brian and R. MacKinnon, Nature, 2002, 415, 287. H. Schlesinger, R. Ferdani, J. Liu, J. Pajewska, R. Pajewski, M. Saito, H. W. Gokel, J. Am. Chem. H. Schlesinger, R. Ferdani, R. Pajewski, J. W. Gokel, Chem. , 2002, 840. G. M. A. Krzycki, Science, 2002, 296, 1459; B. Hao, W. K. M.

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